http://www.researchonline.mq.edu.au/vital/access/services/Feed ${session.getAttribute("locale")} 5 Analysis on variety and characteristics of maghemite http://www.researchonline.mq.edu.au/vital/access/manager/Repository/mq:13246 Maghemite (γ-Fe₂O₃) is a very common mineral at the earth’s surface and also an important material for making music and video tapes. Maghemite is usually synthesized from magnetite under oxidizing conditions after a few hours or a few days below a temperature of 300°C. The magnetic property of thermal instability and the chemical action after heating is an important character for maghemite. That is, it will become hematite in certain proportion after being heated above 250°C. Maghemite is therefore actually unable to have its Curie temperature measured. But late using synthetic sample, maghemite was further found partially thermal stable with a measurable Curie temperature ∼645°C. During our thermally magnetic experiments for a set of synthetic magnetite, we found that extra fined grain size (pseudo single domain (PSD) and small multi-domain (MD), mainly 1–10 μm) magnetite was formed to a completely thermally stable maghemite. This maghemite can also be produced by heating the same powder up to 700°C in an oven and keeping this temperature for 10 min, then cooling it down. When the generated maghemite by these two ways is heated from room temperature to 700°C, it shows almost fully reversible, or thermally stable. We used X-ray powder diffraction and Mössbauer spectroscopy to confirm the identity of this maghemite and compared its magnetic hysteresis, high temperature magnetization, low temperature thermal demagnetization, and low temperature susceptibility with those of the original preheated magnetite. Such quickly oxidized maghemite by heating to high temperature implies some types of maghemite formed in certain natural condition can carry a thermal remnant magnetization (TRM). Four types of maghemite were characterized and discussed according to their thermal stability. Among them, partially stable and fully thermally stable maghemite after heating should possess capability of carrying TRM. There is possibly a compensation of synthetizing maghemite between heating temperature and heating duration. The thermal stability of maghemite may be affected by a few factors, such as its purity (stoichiometry), heating temperature and duration. The grain size may be one of important factors. Maghemite might be similar to magnetite, having various magnetic properties corresponding to its grain size categories such as superparamagnetic (SP), single domain (SD) and MD. Low temperature measurement for PSD fine grain of synthetic magnetite shows a phenomenon of Verwey transition “suppressed”, its fundamental causes could be that the core diameter of oxidized magnetite is actually reach or approach SD size, so that its Verwey transition is shown “suppressed”. 2011-05-25T21:42:13.797Z ]]> Return to Black Mountain : palaeomagnetic reassessment of the Chatsworth and Ninmaroo formations, western Queensland, Australia http://www.researchonline.mq.edu.au/vital/access/manager/Repository/mq:5738 Palaeomagnetic results from late Middle Cambrian–Early Ordovician carbonate sequences sampled at Black Mountain (Mt Unbunmaroo), Mt Datson and near Chatsworth Station (southeastern Georgina Basin) are presented. A palaeomagnetic reassessment of these carbonates was designed in an effort to constrain regional magnetization ages as results from an earlier study, conducted at Mt Unbunmaroo, play a pivotal role in a proposed Cambrian inertial interchange true polar wander (IITPW) event. Remanent magnetizations within these carbonates were found to be variably developed with most specimens displaying two of the five isolated components. Component PF, for which goethite is the identified remanence carrier, is thought to reflect a chemical remanent magnetization of recent origin. Component TR, held by haematite, has a palaeomagnetic pole consistent with the Tertiary segment of Australia's apparent polar wander path (APWP) and most probably was acquired as a consequence of prolonged weathering during this period. The A component has a palaeomagnetic pole at 54.7°S, 262.3°E (dp= 2.3°, dm= 4.5°) after unfolding. This direction, constrained by positive fold and reversal test statistics, is consistent with Australia's Early Devonian APWP, perhaps reflecting a remagnetization event associated with the intracratonic Alice Springs Orogeny. A Late Ordovician–Early Silurian remanence, component B, is also described; with 100 per cent unfolding the associated palaeopole lies at 8.0°S, 216.8°E (dp= 2.6°, dm= 5.1°) . A third Palaeozoic, and presumed primary or early diagenetic, component, C, also passes applied fold and reversal tests and has a palaeomagnetic pole at 48.6°N, 186.0°E (dp= 2.1°S, dm= 4.0°) . This palaeopole is dissimilar from younger magnetizations, is consistent with Cambrian poles from other parts of cratonic Australia and falls within a cluster of Middle–Late Cambrian (515–500 Ma) palaeopoles from other Gondwanan continents. The age attributed to the palaeopole associated with the C component, ~510 Ma, provides a tight constraint on the younger boundary of the proposed Cambrian IITPW event and its agreement with other Gondwanan palaeopoles is incompatible with the IITPW hypothesis. Components A, B and C are analogous to palaeomagnetic results reported in the earlier investigation of this region, and a comparison of results from the two studies, coupled with rigorous statistical analyses of the new findings, is presented. 2010-01-27T22:27:05.816Z ]]>