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Date: 2016
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/1194102
Description: Strategies for combining the selectivity and efficiency of homogeneous organometallic catalysts with the versatility of heterogeneous catalysts are urgently needed. Herein a direct and modular methodo ... More
Full Text: Full Text
Reviewed: Reviewed
Date: 2016
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/1192893
Description: A series of Ru(II) complexes were synthesised based on a hemilabile pyrazole-N-heterocyclic carbene (NHC)-pyrazole (C₃N₂H₃)CH₂(C₃N₂H₂)CH₂(C₃N₂H₃) NCN pincer ligand 1. All complexes were fully characte ... More
Reviewed: Reviewed
Date: 2015
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/1236030
Description: Bimetallic catalysts are capable of activating alkynes to undergo a diverse array of reactions. The unique electronic structure of alkynes enables them to coordinate to two metals in a variety of diff ... More
Date: 2015
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/1046045
Description: A series of bimetallic N-heterocyclic carbene Rh(I) complexes (13, 14, 16, 18, 19, and 21) were prepared, in which two metal fragments are linked to a central organic scaffold. These complexes were in ... More
Reviewed: Reviewed
Date: 2015
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/1051561
Description: An operationally simple and atom-economical method for the E-selective preparation of enol ethers is described. A novel dicarbonyl(5-phenyldipyrrinato)rhodium complex, 2, was prepared in four syntheti ... More
Reviewed: Reviewed
Date: 2015
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348437
Description: Pure carbon black (CB) was covalently attached to a bidentate nitrogen coordination motif with a carbon-carbon bond by spontaneous reaction with an in situ generated ligand precursor. The functionaliz ... More
Reviewed: Reviewed
Date: 2014
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/337434
Description: Two new pincer ligands have been developed that contain a central N-heterocyclic carbene (NHC) moiety linked to two pendant pyrazole groups by either a methylene (NCNme) or ethylene (NCNet) chain. The ... More
Reviewed: Reviewed
Date: 2014
Language: eng
Resource Type: conference paper abstract
Identifier: http://hdl.handle.net/1959.14/1235406
Description: Bimetallic catalysts, both homo- and heterobimetallic, can exhibit unique cooperative properties such as enhanced reaction rates and selectivities in comparison to their monometallic counterparts. The ... More
Date: 2014
Language: eng
Resource Type: conference paper abstract
Identifier: http://hdl.handle.net/1959.14/1222409
Description: Well defined carbon-based catalyst scaffolds have the potential to provide economical and practical routes to a range of high value compounds due to their well defined nanostructure, relatively defect ... More
Date: 2014
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/335877
Description: Three series of ruthenium complexes with the general formula Ru(bpy)n(β-diketonato)₃-n (bpy = 2,2'-bipyridine, n = 0, 1, 2) were prepared and investigated using cyclic voltammetry and UV-vis spectrosc ... More
Reviewed: Reviewed
Date: 2014
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/337431
Description: The structural characterization of a ¹³CO-labeled Ir(I) complex bearing an P,N-donor ligand (1-[2-(diphenylphosphino)ethyl]pyrazole), [Ir(PyP)(¹³CO)Cl] is demonstrated using a series of tailored solid ... More
Reviewed: Reviewed
Date: 2013
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/339997
Description: 11 page(s)
Reviewed: Reviewed
Date: 2013
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/339934
Description: A series of new cationic Rh(i), Rh(iii) and Ir(iii) complexes containing hybrid bidentate N-heterocyclic carbene-1,2,3-triazolyl donor of general formulae [Rh(CaT)(COD)]BPh₄ (2a-d), [Rh(CaT)(CO)₂]BPh₄ ... More
Reviewed: Reviewed
Date: 2013
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/340004
Description: A large increase in reaction rate was observed for the catalyzed mono- and dihydroalkoxylation of alkynes when structurally constrained bimetallic Rh(I) catalysts with imidazolyl-imine ligands were co ... More
Reviewed: Reviewed