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Date: 2012
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/340031
Description: Insight into the iridium(I)/rhodium(I)-catalyzed hydroamination of 4-pentyn-1-amine was established through comparison of catalysts formed in situ from metal precursors and selected ligands with analo ... More
Reviewed: Reviewed
Date: 2009
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/340203
Description: The methylene-bridged Rh(I) dicarbonyl complex, [Rh(bim)(CO)₂⁺ BPh₄⁻] (1) (bim = bis(N-methylimidazol-2-yl)methane), is an effective catalyst for the intramolecular hydroamination of selected ortho-al ... More
Reviewed: Reviewed
Date: 2009
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/340168
Description: A series of novel cationic and neutral rhodium and iridium complexes containing bidentate phosphine-imidazolyl donor ligands of the general formulae [M(ImP)(COD)]BPh4 (M = Rh, ImP = ImP2, 3; ImP1a, 4a ... More
Reviewed: Reviewed
Date: 2007
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348473
Description: A series of cationic rhodium(I) and iridium(I) complexes of the type [M(N−N)(CO)₂][BPh₄] containing the imidazole-based bidentate nitrogen donor ligands (N−N), including bis(N-methylimidazol-2-yl)meth ... More
Reviewed: Reviewed
Date: 2007
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348455
Description: A range of rhodium(I) and iridium(I) complexes containing bidentate phosphine−pyrazolyl ligands of general formulas [M(R₂PyP)(COD)]BPh₄ (R = Me, iPr, Ph, M = Ir, 3b−3d and M = Rh, 4b−4d), [Ir(R₂PyP)(C ... More
Reviewed: Reviewed
Date: 2005
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348405
Description: Cationic Rh(I) and Ir(I) complexes of the form [M(PC)(COD)]BPh4 (M = Rh (4), Ir (5); PC = 3-[2-(diphenylphosphino)ethyl]-1-methylimidazol-2-ylidene) were synthesized by the addition of 3-[2-(diphenylp ... More
Reviewed: Reviewed
Date: 2005
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348368
Description: In the presence of alkylsilanes, the cationic IrI complex [{Ir[bis(pyrazol-1-yl)methane](CO)₂}BPh₄] (1) catalyses the reduction of a range of imines, including N-alkyl and N-aryl imines, and both aldi ... More
Reviewed: Reviewed
Date: 2004
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348700
Description: The dihydrogen hydrido complex [FeH(H₂)(PP₃)]⁺ 1 (PP₃ = P(CH2CH2PMe2)₃ 2) was formed by the protonation of the dihydrido complex FeH₂(PP₃) 3 with methanol or ethanol. The observation of H–D coupling i ... More
Reviewed: Reviewed
Date: 2004
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348742
Description: The cationic Rh(I) dicarbonyl complex [{Rh(bim)(CO)₂}⁺BPh₄⁻] 1, containing a bidentate bisimidazolylmethane ligand [bim refers to bis(N-methylimidazol-2-yl)methane] acts as a catalyst for the cyclizat ... More
Reviewed: Reviewed
Date: 2004
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348865
Description: Cationic rhodium(I) and iridium(I) complexes of the general formula [M(N−N)(CO)₂]⁺[X]-, incorporating the bidentate heterocyclic nitrogen donor ligands (N−N) bis(1-methylimidazol-2-yl)methane (bim) an ... More
Reviewed: Reviewed
Date: 2003
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/349193
Description: The syntheses of five cationic iridium(I) complexes, containing the bidentate ligands bis(1-pyrazolyl)methane (BPM) and bis(3,5-dimethyl-1-pyrazolyl)methane (dmBPM), {[Ir(BPM)(COD)]⁺(BPh₄)⁻} (1), {[Ir ... More
Reviewed: Reviewed
Date: 2003
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348823
Description: The mononuclear cationic RhI complexes [Rh(cod)(mdd)]+X⁻ and [Rh(CO)₂(mdd)]⁺X⁻ (X = BPh₄, PF₆) containing the chelating bidentate N-heterocyclic carbene ligand 1,1′-methylene-3,3′-dimethyldiimidazolin ... More
Reviewed: Reviewed
Date: 2003
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348753
Description: The cationic Ir(I) complex [{Ir(bis(pyrazol-1-yl)methane)(CO)₂}BPh₄] (1) catalyzes the hydroamination of 4-pentyn-1-amine to form 2-methylpyrroline and subsequent hydrosilation to form 1-(triethylsily ... More
Reviewed: Reviewed
Date: 2003
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348851
Description: Cationic iridium(I), rhodium(I) complexes containing bis(1-methylimidazol-2-yl)methane, bim, [M(bim)(CO)₂]BPh₄ (M = Ir(1), Rh(2)); bis(pyrazol-1-yl)methane, bpm, [M(bpm)(CO)₂]BPh₄ (M = Ir (3), Rh(4)) ... More
Reviewed: Reviewed
Date: 2002
Language: eng
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.14/348767
Description: A number of iron(II) compounds containing the poly(1-pyrazolyl)methane ligands bis(1-pyrazoyl)methane (BPM, 3), bis(3,5-dimethyl-1-pyrazolyl)methane (dmBPM, 4), and tris(1-pyrazolyl)methane (TPM, 2), ... More
Reviewed: Reviewed